Preheat your oven to 350°F. Grease two 8-inch round cake pans, line them with parchment paper, then butter and flour the pans.
In the bowl of an electric mixer, sift together the flour, sugar, cocoa, baking soda, baking powder, and salt. Mix on low speed to combine.
Whisk together the whey, vegetable oil, eggs, and vanilla in a separate bowl.
With the mixer on low, slowly pour the wet ingredients into the dry ingredients.
While still on low speed, mix the hot coffee until combined. Scrape the bottom of the bowl to ensure everything is well-mixed.
Divide the batter evenly between the prepared pans and bake for 35-40 minutes or until a cake tester comes out clean.
Let the cakes cool in the pans for 30 minutes, then turn them onto a wire rack to cool completely.